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1,5-Polymerization of vinylcyclopropane

✍ Scribed by Takahashi, T. ;Yamashita, I.

Publisher
Wiley (John Wiley & Sons)
Year
1965
Tongue
English
Weight
156 KB
Volume
3
Category
Article
ISSN
0449-2986

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📜 SIMILAR VOLUMES

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✍ Norbert Moszner; Frank Zeuner; Thomas Völkel; Volker Rheinberger 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 222 KB 👁 1 views

Vinylcyclopropanes are important synthetic intermediates in organic chemistry and are mostly synthesized by the simultaneous introduction of the cyclopropane and the vinyl unit, e. g., by the reaction of trans-1,4-dihalobutenes with b-dicarbonyl compounds or the addition of carbenes to dienes. The p

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## Abstract **Summary:** The photoinitiated cationic polymerization of 1‐cyclopropyl‐l‐phenyl‐ethylene, 1‐cyclopropyl‐l‐(__p__‐methoxyphenyl)ethylene and 1‐cyclopropyl‐l‐(__p__‐fluorophenyl)ethylene at ambient temperatures in bulk and in solution was investigated using (__η__^5^‐2,4‐cyclopentadiene

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Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym

Polymerization of cyclic monomers. VII.
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✍ Norbert Moszner; Frank Zeuner; Thomas Völkel; Urs Karl Fischer; Volker Rheinberg 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 1 views

1,3-Bis[(1-alkoxycarbonyl-2-vinylcyclopropane-1-yl)carboxy]benzenes 1 [RO: CH 3 O (a), C 2 H 5 O (b)] were synthesized by the esterification of the corresponding 1-alkoxycarbonyl-2-vinylcyclopropane-1-carboxylic acids with resorcinol. The structure of the new vinylcyclopropanes was confirmed by elem