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14N/15N Isotope Effect on the Electron Transfer Process between N,N,N‘,N‘-Tetramethyl-p-phenylenediamine and Wurster's Blue

✍ Scribed by Lü, Jian-Ming; Wen, Xiao-Lin; Wu, Long-Ming; Liu, You-Cheng; Liu, Zhong-Li


Book ID
111875413
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
127 KB
Volume
105
Category
Article
ISSN
1089-5639

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14N/15N ISOTOPE EFFECT ON THE ELECTRON T
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An appreciable equilibrium isotope effect has been observed for electron transfer from phenothiazine (PT) to the radical cation of its 15 N-substituted analogue ([ 15 N]PT +• ), i.e. ## PT+[ 15 N]PT +• K PT +• +[ 15 N]PT via electron paramagnetic resonance analysis of the mixed radical cations fo