Optical spectra (1 to 6 eV) of the neutral electron donor-acceptor complex TMPD-CA have been obtained in different solvents includins polar ones such as acetonitie\_ The optical spectra. the dielectric constant and the ESR absorption have been studied in detail as a function of temperature, in the r
Photoinduced Electron Transfer in Donor−Acceptor Aryl Dyads Based on N , N , N ‘, N ‘-Tetramethyl- p -phenylenediamine as the Donor
✍ Scribed by Fossum, Renae D.; Fox, Marye Anne; Gelormini, Ann M.; Pearson, Anthony J.
- Book ID
- 121226284
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 210 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0022-3654
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Photoinduced electron transfer (ET) is studied in a series of novel molecules containing a dimethoxynaphthalene (DMN) donor and either a pyridine (P) or N-methylpyridinium (P-Me + ) acceptor covalently linked via a rigid norbornalogous bridge (n sigma bonds in length). ET rates of the order of l0 ~°
The stability constant of the EDA complex between N,Ar,N',N'-tetramethyl-p-phenylendiamine and m-dinitrobenzene in acetonitrile has been studied by cyclic voltammetry and potentiometric titration at constant finite current. For comparison, spectral measurements were made. The spectroscopic technique