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14 N/ 15 N and 12 C/ 13 C Equilibrium Isotope Effects on the Electron-Transfer Reaction between N -Methylphenothiazine and Its Radical Cation

✍ Scribed by Lü, Jianming; Chen, Yadong; Wen, Xiaoling; Wu, Long-Min; Jia, Xueqing; Liu, You-Cheng; Liu, Zhong-Li


Book ID
126298412
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
194 KB
Volume
103
Category
Article
ISSN
1089-5639

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An appreciable equilibrium isotope effect has been observed for electron transfer from phenothiazine (PT) to the radical cation of its 15 N-substituted analogue ([ 15 N]PT +• ), i.e. ## PT+[ 15 N]PT +• K PT +• +[ 15 N]PT via electron paramagnetic resonance analysis of the mixed radical cations fo