14N/15N ISOTOPE EFFECT ON THE ELECTRON T
14N/15N ISOTOPE EFFECT ON THE ELECTRON TRANSFER PROCESS BETWEEN PHENOTHIAZINE AND ITS RADICAL CATION
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Long-Min Wu; Jian-Ming Lü; Xiao-Lin Wen; Xue-Qing Jia; You-Cheng Liu; Zhong-Li L
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Article
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1997
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John Wiley and Sons
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English
⚖ 181 KB
An appreciable equilibrium isotope effect has been observed for electron transfer from phenothiazine (PT) to the radical cation of its 15 N-substituted analogue ([ 15 N]PT +• ), i.e. ## PT+[ 15 N]PT +• K PT +• +[ 15 N]PT via electron paramagnetic resonance analysis of the mixed radical cations fo