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1,3,5-Triamino-1,3,5-trideoxy- cis -inositol and all-cis -2,4,6-Trimethoxycyclohexane- 1,3,5-triamine as Building Blocks for New Multidentate and Macrocyclic Ligands 1

✍ Scribed by Hegetschweiler, Kaspar; Weber, Michael; Huch, Volker; Geue, Rodney J.; Rae, A. David; Willis, Anthony C.; Sargeson, Alan M.

Book ID: 126111078
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 186 KB
Volume: 37
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic980483w

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## Abstract The two neutral complexes [Re(CO)~3~(H~−1~taci)] (1) and [ReO~3~(H~−1~taci)] (2) (taci=1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol) were synthesized from the conventional Re^I^ and Re^VII^ precursors (Et~4~N)~2~[ReBr~3~(CO)~3~] and [ReO~3~(OSnMe~3~)]. The crystal structures of 1 and

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## Abstract A new, convenient, and safe route to 1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol (taci) was investigated by hydrogenation of azo‐coupled derivatives of phloroglucinol. In the presence of acetic anhydride, the reduction of trisphenylazophloroglucinol (H~2~/Pd(5%) on C) resulted in the