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Complex Formation of Vanadium(IV) with 1,3,5-Triamino-1,3,5-trideoxy- cis -inositol and Related Ligands †

✍ Scribed by Morgenstern, Bernd; Steinhauser, Stefan; Hegetschweiler, Kaspar; Garribba, Eugenio; Micera, Giovanni; Sanna, Daniele; Nagy, László

Book ID: 127356159
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 197 KB
Volume: 43
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic0352046

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## Abstract The two neutral complexes [Re(CO)~3~(H~−1~taci)] (1) and [ReO~3~(H~−1~taci)] (2) (taci=1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol) were synthesized from the conventional Re^I^ and Re^VII^ precursors (Et~4~N)~2~[ReBr~3~(CO)~3~] and [ReO~3~(OSnMe~3~)]. The crystal structures of 1 and