Lipophilic Ligands Derived from 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol (Taci) for Trivalent Lanthanide Complexation in Aqueous and Organic Solutions
✍ Scribed by Samuel Delagrange; Christelle Gateau; David Chapon; Colette Lebrun; Pascale Delangle; Philippe Vottéro
- Book ID
- 101349707
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 169 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The complexes [Fe(tdci)~2~]Cl~3~ and [Al(tdci)~2~]Cl~3~ (tdci = 1,3,5‐trideoxy‐1,3,5‐tris(dimethylamino)‐__cis__‐inositol) were prepared and characterized by mass spectrometry, NMR spectroscopy, and magnetic‐susceptibility measurements. The formation constants were determined in aqueous
## Abstract The two neutral complexes [Re(CO)~3~(H~−1~taci)] (1) and [ReO~3~(H~−1~taci)] (2) (taci=1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol) were synthesized from the conventional Re^I^ and Re^VII^ precursors (Et~4~N)~2~[ReBr~3~(CO)~3~] and [ReO~3~(OSnMe~3~)]. The crystal structures of 1 and
## Abstract A new, convenient, and safe route to 1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol (taci) was investigated by hydrogenation of azo‐coupled derivatives of phloroglucinol. In the presence of acetic anhydride, the reduction of trisphenylazophloroglucinol (H~2~/Pd(5%) on C) resulted in the