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O-Alkylated Derivatives of 1,3,5-Triamino-1,3,5-trideoxy- cis -inositol: Triamine Ligands with Unexpectedly High Affinity toward Divalent Transition- and d 10 -Metal Ions

✍ Scribed by Weber, Michael; Kuppert, Dirk; Hegetschweiler, Kaspar; Gramlich, Volker


Book ID
127296954
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
189 KB
Volume
38
Category
Article
ISSN
0020-1669

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1,3,5-Triamino-1,3,5-trideoxy-cis-inosit
✍ Michele Ghisletta; Kaspar Hegetschweiler; Hans-Peter Jalett; Tobias Gerfin; Volk 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 German ⚖ 547 KB

## Abstract A new, convenient, and safe route to 1,3,5‐triamino‐1,3,5‐trideoxy‐__cis__‐inositol (taci) was investigated by hydrogenation of azo‐coupled derivatives of phloroglucinol. In the presence of acetic anhydride, the reduction of trisphenylazophloroglucinol (H~2~/Pd(5%) on C) resulted in the