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1,3,4,5-Tetraphenylimidazol-2-ylidene: The Realization of Wanzlick's Dream

โœ Scribed by Anthony J. Arduengo III; Jens R. Goerlich; Roland Krafczyk; William J. Marshall


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
100 KB
Volume
37
Category
Article
ISSN
0044-8249

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## Abstract 2,3โ€Dihydroโ€1,3โ€diisopropylโ€4,5โ€dimethylimidazolโ€2โ€ylidene **1** (Carb, R^1^ = ^i^Pr, R^2^ = Me) reacts with TeI~4~ to give the carbene adduct CarbTeI~2~ (**3**). The crystal structure of **3** consists of Tโ€shaped monomeric fragments linked by weak Te. I interactions to form infinite h