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Reaction of tellurium tetraiodide with 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene

✍ Scribed by Norbert Kuhn; Ahmed Abu-Rayyan; Carla Piludu; Manfred Steimann

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 83 KB
Volume: 16
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20090

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✦ Synopsis

Abstract

2,3‐Dihydro‐1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene 1 (Carb, R^1^ = ^i^Pr, R^2^ = Me) reacts with TeI~4~ to give the carbene adduct CarbTeI~2~ (3). The crystal structure of 3 consists of T‐shaped monomeric fragments linked by weak Te. I interactions to form infinite helical chains. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:316–319, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20090

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## Abstract For Abstract see ChemInform Abstract in Full Text.