𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Nucleophilic Aromatic Substitution with 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene.

✍ Scribed by Eyad Mallah; Norbert Kuhn; Caecilia Maichle-Moessmer; Manfred Steimann; Markus Stroebele; Klaus-Peter Zeller

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
41
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

{Ph2(Carb)P}MCl3 (M = Pd, Pt; Carb = 2,3
{Ph2(Carb)P}MCl3 (M = Pd, Pt; Carb = 2,3-dihydro-1,3-diisopropyl-4,5dimethylimidazol-2-ylidene) – a Novel Cationic Phosphane Ligand [1]
✍ Norbert Kuhn; Gerald Henkel; Martin GΓΆhner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 73 KB πŸ‘ 1 views

The phosphane ligand [Ph 2 (Carb)P] + forms neutral complexes {Ph 2 (Carb)P}MCl 3 (Carb = 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene; M = Pd, Pt) through the reaction of it's chloride salt with (PhCN) 2 MCl 2 ; the triarylphosphane type properties of the ligand are revealed by n.m.r.

Synthese und Eigenschaften von [Ph2(Carb
Synthese und Eigenschaften von [Ph2(Carb)P]AlCl4 (Carb = 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-yliden) – ein stabiler Carben-Komplex des dreiwertigen Phosphors [1]
✍ Norbert Kuhn; Joanna Fahl; Dieter BlΓ€ser; Roland Boese πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 126 KB πŸ‘ 1 views

Inhaltsu È bersicht. 2, Carb) reagiert mit Chlordiphenylphosphan zum kationischen Phosphan [Ph 2 (Carb)P]Cl (10), das mit AlCl 3 in das stabilere Salz [Ph 2 (Carb)P]AlCl 4 (13) u È berfu È hrt wird. Das kationische Phosphanselenid [Ph 2 (Carb)PSe]AlCl 4 (14) wird aus 13 und Selen erhalten. Spektros