ChemInform Abstract: Chemical Reactions of the Stable Carbene 1,3,4-Triphenyl-4,5-dihydro- 1H-1,2,4-triazol-5-ylidene.
โ Scribed by D. ENDERS; K. BREUER; J. RUNSINK; J. H. TELES
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
1997 triazole derivatives
triazole derivatives R 0280
12 -123
Chemical Reactions of the Stable Carbene 1,3,4-Triphenyl-4,5dihydro-1H-1,2,4-triazol-5-ylidene.
-Insertion reactions to afford (IV), addition reactions to give (V) and (VII), cycloaddition reactions to yield (IX) and (XI), and reactions with heterocumulenes, e.g. (XIII), leading to the spiro compound (XIV) are described for the stable carbene (II) or its precursor (I). Compound (II) acts like a typical nucleophilic carbene. -(ENDERS, D.;
๐ SIMILAR VOLUMES
1997 triazole derivatives triazole derivatives R 0280 ## 09 -110 A Study on 4,5-Dihydro-1H-1,2,4-triazol-5-ones. -Phthalimides like (V) are obtained by the reaction of the title triazoles (IV) with phthalic anhydride at high temperature. In the case of compound (I) and (VI) the reaction gives the