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[11,23-Dimethyl-15,19-diaza-3,7-diazo­niatricyclo­[19.3.1.19,13]tetracosa-1(25),2,7,9,11,13(26),14,19,21,23-deca­ene-25,26-diolato-κ4N15,N19,O,O′]tris­(nitrato-κ2O,O′)samarium(III)

✍ Scribed by d′Hardemare, Amaury du Moulinet ;Philouze, Christian ;Jarjayes, Olivier


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
201 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title complex, [Cu(C 36 H 36 N 4 O 4 )(ClO 4 )](ClO 4 )ÁC 3 H 7 N, the coordination number of the Cu II atom is 5 and the coordination configuration is best described as distorted tetragonal-pyramidal. There is a 13-membered macrocyclic ring in the molecule. One perchlorate anion and the dime