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1-[N-Methyl-N-(4-methyl­benz­yl)amino­meth­yl]ferrocene

✍ Scribed by Wang, Hong-Xing ;Wu, Hong-Fei ;Geng, Feng-Ying ;Gao, Ren-Qing ;Zhou, Hui-Chao

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
106 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, [PdCl{Fe(C 5 H 5 )(C 15 H 17 NO)}-(C 18 H 15 P)] or [FePd(C 5 H 5 )(C 15 H 17 NO)Cl(C 18 H 15 P)], the Pd II atom is in a slightly distorted square-planar environment. The dihedral angle between the two cyclopentadienyl rings of the ferrocenyl group is 6.4 (1) .

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1,1′-Bis{α-[(4-methyl­benz­yl)imino]benz­yl}ferrocene
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The title compound, [Fe(C~20~H~18~N)~2~], a new 1,1′-disubstituted ferrocenylketimine derivative, has been synthesized and characterized. All the bond lengths are within normal range.

N-(4-Methyl­benz­yl)phthalimide
N-(4-Methyl­benz­yl)phthalimide
✍ Chen, Ping ;Zhang, Ling ;Li, Dan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 90 KB

The title compound, C 16 H 13 NO 2 , was synthesized by Nalkylation of 4-methylbenzyl bromide with phthalimide. The phthalimide ring system is essentially planar and forms a dihedral angle with the tolyl ring of 69.5 (6) .

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1,4-Bis{N-[4-(ethoxy­carbon­yl)benz­yl]-N-(4-tolyl­sulfon­yl)amino­meth­yl}benzene
✍ Nieger, Martin ;Schwierz, Holger ;Vögtle, Fritz 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

The title compound, C 42 H 44 N 2 O 8 S 2 , features a molecular thread. The molecules have crystallographic C i symmetry. The crystal packing shows staples stabilized by weak C-HÁ Á ÁO interactions.