1-{[N-Methyl-N-(4-methylphenyl)amino]methyl}ferrocene
✍ Scribed by Wang, Hong-Xing ;Li, Ying-Jie ;Wu, Hong-Fei ;Zhou, Hui-Chao ;Geng, Feng-Ying ;Gao, Ren-Qing
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 119 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.
In the crystal structure of the title complex, C 21 H 21 N, the molecule lies on a twofold rotation axis. The N atom is sp 2 hybridized. Comparisons are made with similar compounds in this series.
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.005 A R factor = 0.070 wR factor = 0.133 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 13 H 12 F 3 N 5 O 2 , intramolecular N-HÁ Á ÁF, N-HÁ Á ÁN, C-HÁ Á ÁO and C-HÁ Á ÁN hydrogen bonds, andstacking interactions generate a columnar structure along the a axis.