✦ LIBER ✦

1-(4-Nitrobenzoyl)-3-phenylthiourea

✍ Scribed by Saeed, Aamer ;Bolte, Michael

Book ID: 104491473
Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 952 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807034587

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✦ Synopsis

Geometric parameters of the title compound, C 14 H 11 N 3 O 3 S, are in the usual ranges. The molecular conformation is stabilized by an N-HÁ Á ÁO hydrogen bond. In the crystal structure, the molecules form centrosymmetric dimers connected by N-HÁ Á ÁS hydrogen bonds. The molecule is almost planar (r.m.s. deviation for all atoms = 0.268 A ˚); only the torsion angles about the C-C bond between the carbonyl group and the nitrophenyl ring [O-C-C-C = À157.92 (16) ] and about the C-N bond between the phenyl ring and the amide group [C-N-C-C = 15.9 (3) ] differ significantly from 0 or 180 .

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