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1-(2,4-Dichloro­benzo­yl)-3-phenyl­thio­urea

✍ Scribed by Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael ;Ahmad, Imtiaz

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
192 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C~14~H~10~Cl~2~N~2~OS, crystallizes with two molecules in the asymmetric unit. The two molecules, differing only in the conformation of the dichlorophenyl ring, show the typical geometric parameters of substituted thiourea derivatives. The crystal packing is characterized by N—H...O and N—H...S hydrogen bonds.

📜 SIMILAR VOLUMES

1-(2,4-Dichloro­benzo­yl)-3-(3,4-dichlor
1-(2,4-Dichloro­benzo­yl)-3-(3,4-dichloro­phen­yl)thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

The title compound, C 14 H 8 Cl 4 N 2 OS, shows the typical geometric parameters of substituted thiourea derivatives. The dihedral angle formed by the two benzene ring planes is 38.39 (7) . The crystal packing is characterized by N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds.

1-(2,6-Dichloro­benzo­yl)-3-(3,4-dichlor
1-(2,6-Dichloro­benzo­yl)-3-(3,4-dichloro­phen­yl)thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael ;Ahmad, Imtiaz 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

The title compound, C~14~H~8~Cl~4~N~2~OS, shows the typical geometric parameters of substituted thiourea derivatives. The crystal packing is characterized by N—H...O and N—H...S hydrogen bonds.

1-(4-Chloro­phen­yl)-3-(2,6-dichloro­ben
1-(4-Chloro­phen­yl)-3-(2,6-dichloro­benzo­yl)thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

The title compound, C 14 H 9 Cl 3 N 2 OS, shows the typical geometric parameters of substituted thiourea derivatives. The crystal packing is characterized by N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds.

1-(2-Chloro­benzo­yl)-3-phenyl­thio­urea
1-(2-Chloro­benzo­yl)-3-phenyl­thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Saeed, Aamer ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 107 KB

The phenyl and benzoyl groups in the title molecule, C~14~H~11~ClN~2~OS, are __cis__ and __trans__, respectively, with respect to the C=S bond. The molecular conformation is stabilized by an N—H...O hydrogen bond and the crystal packing is characterized by N—H...O and N—H...S hydrogen bonds.

1-(2-Chloro­phen­yl)-3-(2,6-dichloro­ben
1-(2-Chloro­phen­yl)-3-(2,6-dichloro­benzo­yl)thio­urea toluene hemisolvate
✍ Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael ;Imtiaz-ud-Din, 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 121 KB

In the title compound, C 14 H 9 Cl 3 N 2 OSÁ0.5C 7 H 8 , the toluene molecule is disordered over a centre of inversion. The dihedral angle formed by the two benzene ring planes is 2.26(8) .