𝔖 Bobbio Scriptorium
✦   LIBER   ✦

σ-Bonded Metal Carbonyl Cations and Their Derivatives: Syntheses and Structural, Spectroscopic, and Bonding Principles †

✍ Scribed by Willner, Helge; Aubke, Friedhelm

Book ID
126785657
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
532 KB
Volume
22
Category
Article
ISSN
0276-7333

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Predominantly σ-Bonded Metal Carbonyl Ca
Predominantly σ-Bonded Metal Carbonyl Cations (σ-Carbonyls): New Synthetic, Structural, and Bonding Concepts in Metal Carbonyl Chemistry
✍ Helge Willner; Friedhelm Aubke 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 244 KB 👁 1 views

## Abstract Predominantly σ‐bonded metal carbonyl cations (σ‐carbonyls) are conveniently generated in the Lewis superacid SbF~5~ or the conjugate Brønsted–Lewis superacid HFSbF~5~, primarily by solvolytic or reductive carbonylations. Thermally stable salts are formed with the fluoroantimonate(V) i