μ-Terephthalato-bis[aquachloro(1,10-phenanthroline)copper(II)] μ-terephthalato-bis[diaqua(1,10-phenanthroline)cuprate(II)] dichloride dihydrate
✍ Scribed by Chen, Fan ;Li, Xin-Hua ;Xiao, Hong-Ping ;Hu, Mao-Lin
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 210 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
l-Terephthalato-bis[aquachloro(1,10-phenanthroline)copper(II)] l-terephthalato-bis-[diaqua(1,10-phenanthroline)cuprate(II)] dichloride dihydrate
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê R factor = 0.089 wR factor = 0.167 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the structure of the title complex, [Mn 2 (C 8 H 4 O 4 )Cl 2 -(C 12 H 8 N 2 ) 2 ], each Mn II cation is surrounded by two O atoms from two terephthalate dianions, two bridging Cl atoms and two N atoms from a 1,10-phenanthroline molecule in a distorted octahedral geometry. Each terephthalate diani
Each Cu atom in the centrosymmetric dinuclear title compound, [Cu 2 (C 3 H 5 O 5 P) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ], is chelated by an N-heterocycle and is also coordinated by a molecule of water. The two Cu atoms are bridged by the 3-phosphonopropionate(2À) unit, giving rise to a square-pyramidal g
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.010 A Ê Disorder in solvent or counterion R factor = 0.084 wR factor = 0.172 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.