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Poly[di-μ-chloro-bis­(1,10-phenanthroline)-μ4-terephthalato-dimanganese(II)]

✍ Scribed by Sun, Jian-Hua ;Shang, Tong-Ming

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
435 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the structure of the title complex, [Mn 2 (C 8 H 4 O 4 )Cl 2 -(C 12 H 8 N 2 ) 2 ], each Mn II cation is surrounded by two O atoms from two terephthalate dianions, two bridging Cl atoms and two N atoms from a 1,10-phenanthroline molecule in a distorted octahedral geometry. Each terephthalate dianion functions as a 4 -bridging ligand to form a zigzag chain. Neighbouring chains are held together by -chloro bridges, which create a three-dimensional architecture.

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