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μ-Terephthalato-bis­[aqua­chloro(1,10-phenanthroline)copper(II)]

✍ Scribed by Xiao, Hong-Ping ;Li, Xin-Hua ;Ye, Ming-De ;Hu, Mao-Lin


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
494 KB
Volume
60
Category
Article
ISSN
1600-5368

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μ-Terephthalato-bis­[chloro(1,10-phenant
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê R factor = 0.089 wR factor = 0.167 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the structure of the title complex, [Mn 2 (C 8 H 4 O 4 )Cl 2 -(C 12 H 8 N 2 ) 2 ], each Mn II cation is surrounded by two O atoms from two terephthalate dianions, two bridging Cl atoms and two N atoms from a 1,10-phenanthroline molecule in a distorted octahedral geometry. Each terephthalate diani

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Each Cu atom in the centrosymmetric dinuclear title compound, [Cu 2 (C 3 H 5 O 5 P) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ], is chelated by an N-heterocycle and is also coordinated by a molecule of water. The two Cu atoms are bridged by the 3-phosphonopropionate(2À) unit, giving rise to a square-pyramidal g