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μ-Oxo bridged diiron(III) complexes and hydrogen peroxide: oxygenation and catalase-like activities

✍ Scribed by Okuno, Takashi; Ito, Sayo; Ohba, Shigeru; Nishida, Yuzo

Book ID
121390087
Publisher
The Royal Society of Chemistry
Year
1997
Tongue
English
Weight
145 KB
Volume
19
Category
Article
ISSN
1472-7773

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The new diiron complex [Fe 2 (tbpo){O 2 As(CH 3 ) 2 }(CH 3 O)-hydroxo-bridged complex [Fe 2 (tbpo)(OH)(NO 3 ) 2 ](NO 3 ) 2 • CH 3 OH • 2 H 2 O (2) was employed. The reactions of 1 and 2 with H 2 O 2 were studied as a function of [H 2 O 2 ], pH, temperature, and pressure, and the kinetic results inc