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DNA binding and oxidative DNA cleavage activity of (μ-oxo)diiron(iii) complexes in visible light

✍ Scribed by Roy, Mithun ;Santhanagopal, Ramkumar ;Chakravarty, Akhil R.

Book ID
120734231
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
375 KB
Volume
6
Category
Article
ISSN
1477-9226

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## Abstract The complex ion [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) (phen = 1,10‐phenanthroline) and its hydrolytic derivatives [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)(OH)]^3+^ (1a) and [Fe^III^~2~(μ‐O)(phen)~4~‐ (OH)~2~]^2+^ (2a) coexist in rapid equilibria in the range pH 4.23–5.35 in the presence