Synthesis, Structure, and Catalytic Activity of New μ-Oxo-Bridged Diiron(III) Complexes
✍ Scribed by Éva Balogh-Hergovich; Gábor Speier; Marius Réglier; Michel Giorgi; Ernő Kuzmann; Attila Vértes
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 149 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A new dialkoxo‐bridged diiron(III) complex, [Fe~2~(BMA)~2~(CH~3~O)~2~Cl~2~]·2Cl·4CH~3~OH (1) [BMA = __N__,__N__‐bis(2‐benzimidazolylmethyl)amine], was synthesized and characterized by UV‐visible absorption and infrared spectra and magnetic susceptibilities. The complex crystallizes in t
The new diiron complex [Fe 2 (tbpo){O 2 As(CH 3 ) 2 }(CH 3 O)-hydroxo-bridged complex [Fe 2 (tbpo)(OH)(NO 3 ) 2 ](NO 3 ) 2 • CH 3 OH • 2 H 2 O (2) was employed. The reactions of 1 and 2 with H 2 O 2 were studied as a function of [H 2 O 2 ], pH, temperature, and pressure, and the kinetic results inc
## Abstract For Abstract see ChemInform Abstract in Full Text.
duction indicating destruction of the indacene structure. At an even higher negative potential reversible reduction of the phenylanthracene substructure can be observed. Apparently the substructures are electrochemically independent, too. Cyclic voltammetry of 4 a indicated that the oxidation of th