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μ-[1,2-Bis(diethylphosphino)ethane]-P:P'-bis[bis(diethyldithiocarbamato-S,S')zinc(II)] ditoluene solvate

✍ Scribed by Zeng, D. ;Hampden-Smith, M. J. ;Larson, E. M.


Book ID
114510763
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
309 KB
Volume
50
Category
Article
ISSN
0108-2701

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μ-Bis­(di­phenyl­phosphino)­ethane-P,P′-
✍ Beer, Stephan ;Lai, Chian Sing ;Halbach, Tobias S. ;Tiekink, Edward R. T. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

The molecular structure of the title compound, [Zn 2 (C 4 H 7 OS 2 ) 4 (C 26 H 24 P 2 )], features two Zn(S 2 COiPr) 2 units bridged by a diphosphine ligand. The thiolate ligands are chelating but form asymmetric ZnÐS bonds, introducing considerable distortion in the coordination geometry about Zn t