The title compound, [Zn 2 (NO 3 ) 2 (C 22 H 30 N 4 O 2 )], is a centrosymmetric dinuclear zinc compound. Each Zn atom has a square-pyramidal geometry with N 2 O 3 donors, being coordinated by two N atoms and two O atoms from the macrocyclic 10, 21-dimethyl-3,6,14,17-tetraazatricyclo[17.3.1 8,12 ]tet
[μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.1 8,12 ]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ 8N 3 , N 6 , O 23 , O 24 : N 14 , N 17 , O 23 , O 24 ]bis[(nitrato-κ 2O , O ′)nickel(II)]
✍ Scribed by Li, Quan-Jun; Ma, Jian-Fang; Liu, Jie; Han, Ting-Ting
- Book ID
- 121670482
- Publisher
- International Union of Crystallography
- Year
- 2009
- Tongue
- English
- Weight
- 478 KB
- Volume
- 65
- Category
- Article
- ISSN
- 1600-5368
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The title complex, [Cu~2~(C~20~H~16~F~2~N~4~O~2~)(CH~4~O)~2~](ClO~4~)~2~, was synthesized by cyclo-condensation between ethylenediamine and 2,6-diformyl-4-fluorophenol in the presence of Cu^II^ ions. This dinuclear copper complex is centrosymmetric. Both Cu atoms are in a distorted tetrahedral geome
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A Disorder in solvent or counterion R factor = 0.045 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.