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η1, η2-Hetero-bimetallic phospha-alkyne complexes. Synthesis and NMR spectra of [Pt(dppe)(tBuCP)M(CO)5] (M = Cr, Mo, W)

✍ Scribed by Duncan Carmichael; Saud I. Al-Resayes; John F. Nixon

Book ID
103228345
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
283 KB
Volume
453
Category
Article
ISSN
0022-328X

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## Abstract Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.