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13C CP-MAS NMR spectra and fluxional behaviour of [M2(ηHCCCMe2)(CO)4(ηC5H5)2]+ [BF4]− (M = Mo, W) complexes in the solid state

✍ Scribed by M. V. Galakhov; V. I. Bakhmutov; I. V. Barinov

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 180 KB
Volume: 29
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260290516

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✦ Synopsis

Abstract

Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.

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