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Synthesis and characterization of the linear MHgM trimetallic complexes [η5-Bz5C5(CO3M]2Hg and [η5-HO2CC5H4(CO3M]2Hg(M = Cr, Mo, W). The X-ray crystal structure of η5-Bz5C5(CO)3W]2Hg

✍ Scribed by Li-Cheng Song; Lu-Yan Zhang; Zhi-Fu Tao; Qing-Mei Hu; Xiao-Ying Huang

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
434 KB
Volume
16
Category
Article
ISSN
0277-5387

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## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C