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β-Deuterium Isotope Effects on Amine Basicity, “Inductive” and Stereochemical

✍ Scribed by Perrin, Charles L.; Ohta, Brian K.; Kuperman, Joshua

Book ID
126894479
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
47 KB
Volume
125
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

No Contribution of an Inductive Effect t
No Contribution of an Inductive Effect to Secondary Deuterium Isotope Effects on Acidity
✍ Prof. Charles L. Perrin; Agnes Flach 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB

Isotope effects are observed when a reaction rate or equilibrium constant changes as a result of isotopic substitution. [1] They continue to be used as valuable tools to provide insight into molecular structure and reactivity. [2] Secondary isotope effects are those in which the bond to the isotope