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β-Secondary and Solvent Deuterium Kinetic Isotope Effects on β-Lactamase Catalysis †

✍ Scribed by Adediran, S. A.; Deraniyagala, S. A.; Xu, Yang; Pratt, R. F.

Book ID
127322948
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
460 KB
Volume
35
Category
Article
ISSN
0006-2960

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Chorismate synthase (EC 4.6.1.4) is the shikimate pathway enzyme that catalyzes the conversion of 5-enolpyruvylshikimate 3-phosphate (EPSP) to chorismate. The enzyme reaction is unusual because it involves a trans-1,4 elimination of the C-3 phosphate and the C-6 proR hydrogen and it has an absolute