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α-Oxymethyl Ketone Enolates for the Asymmetric Mannich Reaction. From Acetylene and N-Alkoxycarbonylimines to β-Amino Acids

✍ Scribed by Claudio Palomo; Mikel Oiarbide; M. Concepción González-Rego; Arun K. Sharma; Jesús M. García; Alberto González; Cristina Landa; Anthony Linden

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
117 KB
Volume
39
Category
Article
ISSN
0044-8249

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α-Oxymethyl Ketone Enolates for the Asym
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The reactions of enolizable carbonyl compounds with azomethine functions, usually referred to as Mannich-type reactions (also termed aza ± aldol reactions), result in the formation of b-amino acids, ketones, or aldehydes. [1] These reactions are conceptually equivalent to the aldol reactions, but, i

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v