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ChemInform Abstract: Reversal of Diastereoselectivity of the Reaction of Chiral Boron and Titanium Enolates with Nitrones via N-Acyloxyiminium Intermediates. Asymmetric Synthesis of Diastereomeric α-Substituted β-Amino Acids.

✍ Scribed by Toru Kawakami; Hiroaki Ohtake; Hiroaki Arakawa; Takahiro Okachi; Yasushi Imada; Shun-Ichi Murahashi


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ A. DETSI; M. MICHA-SCRETTAS; O. IGGLESSI-MARKOPOULOU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Synthesis of N-Alkoxycarbonyl-3-substituted Tetramic Acids and Functionalized Enols via C-Acylation Reactions of Active Methylene Compounds with N-Hydroxysuccinimide Esters of N-Alkoxycarbonylα-amino Acids. -A new, mild, and advantageous approach is used for the preparation of the title compounds,