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α-Helical Peptide Nucleic Acids (α-PNAs)

✍ Scribed by Philip Garner; Subhakar Dey; Yumei Huang

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract Peptide nucleic acid (PNA) is a nucleobase oligomer in which the entire backbone has been replaced by a backbone composed of __N__‐(2‐aminoethyl)glycine units. In other words, PNA can be regarded as DNA with a neutral peptide backbone instead of a negatively charged sugar–phosphate back

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## Abstract Relevant parameters and stereochemical consequences of helices [α‐helix, 3~10~‐helix, β‐bend ribbon spiral, γ‐helix, 2.0~5~‐helix, poly(Pro)~__n__~ type‐I and ‐II helices, and collagen triple helix] of peptides based on α‐amino acids for use as templates in various branches of chemistry

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Peptide Nucleic Acids (PNAs) are DNA mimics in which the chiral monomer inserted in the middle of the strand is able to induce a strong preference in the helix handedness of a deoxyribose phosphate backbone has been replaced by a pseudo-peptide skeleton composed of N-(2-aminoethyl)-PNA-PNA duplex. T