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α-Fluorocarbonyl compounds by isomerization of 2-fluorooxiranes

✍ Scribed by D. Michel; M. Schlosser


Book ID
103402822
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
359 KB
Volume
52
Category
Article
ISSN
0040-4020

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A convenient new synthesis of α-fluoroca
✍ Albert J. Fry; Yoelit Migron 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 232 KB

The reaction between tertiary a-bromo ketones or aldehydes and silver tetrafluoroborate in ether affords a-fluorocarbonyl compounds. Neighboring group participation by the carbonyl oxygen is proposed to account for the products and by-products. Published methods1 for the synthesis of a-fluoro keto