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Density functional study of the one-bond CF coupling constant in α-fluorocarbonyl and α-fluorosulfonyl compounds

✍ Scribed by Matheus P. Freitas; Michael Bühl


Book ID
113711670
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
925 KB
Volume
140
Category
Article
ISSN
0022-1139

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## Abstract The one‐bond coupling constant ^1^__J__ ^13^CH for the halogenated carbon in α‐halogenocyclohexanones is more important when the CH bond is in the equatorial then in the axial position. When a conformational equilibrium is present, the resulting coupling is a linear function of the eq