α- and β-Thujone Radical Rearrangements and Isomerizations. A New Radical Clock
✍ Scribed by He, Xiang; Ortiz de Montellano, Paul R.
- Book ID
- 127270956
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 117 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3263
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The 147 nm photolysis of 3,3 dimethylbut-l-ene leads mainly to the formation of very hot ( ~3 7 5 kJ/mol) a,a-dimethallyl radicals. On the other hand, that of 3-methyl-cisand trans-pentene-2, as well as that of 2,3-dimethylbut-l-ene is a source of very hot a$-dimethallyl radicals. These allylic radi
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