Isomerization of unsaturated radicals. V
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Hélêne Deslauriers; Guy J. Collin
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Article
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1988
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John Wiley and Sons
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English
⚖ 434 KB
The 147 nm photolysis of 3,3 dimethylbut-l-ene leads mainly to the formation of very hot ( ~3 7 5 kJ/mol) a,a-dimethallyl radicals. On the other hand, that of 3-methyl-cisand trans-pentene-2, as well as that of 2,3-dimethylbut-l-ene is a source of very hot a$-dimethallyl radicals. These allylic radi