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Organic Free Radical-Promoted Isomerization of α- and β-Alkylcobinamides 1

✍ Scribed by Zou, Xiang; Zhao, Daqing; Brown, Kenneth L.


Book ID
126417509
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
236 KB
Volume
35
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES


Isomerization of unsaturated radicals. V
✍ Hélêne Deslauriers; Guy J. Collin 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 434 KB

The 147 nm photolysis of 3,3 dimethylbut-l-ene leads mainly to the formation of very hot ( ~3 7 5 kJ/mol) a,a-dimethallyl radicals. On the other hand, that of 3-methyl-cisand trans-pentene-2, as well as that of 2,3-dimethylbut-l-ene is a source of very hot a$-dimethallyl radicals. These allylic radi