## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
✦ LIBER ✦
ChemInform Abstract: Manganese(III)-Promoted Free Radical Cyclizations of Enamides Leading to β-Lactams.
✍ Scribed by A. D'ANNIBALE; A. PESCE; S. RESTA; C. TROGOLO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 40 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Ceric Ammonium Nitrate Promoted Free Radical Cyclization Reactions Leading to β-Lactams. -Treatment of enamides (I) or (V) with cerium ammonium nitrate (CAN) generates α-carbamoyl radicals which undergo 4-exo-trig cyclization followed by methanol quenching to provide the functionalized β-lactams. T
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## Abstract A new type of terpenoid cyclization by manganese(III)‐initiated oxidation of β‐ketoester, followed by an intramolecular hetero Diels—Alder reaction with the terpenoid chain is investigated.
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