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ChemInform Abstract: Free Radical Cyclization of Enamides Leading to Biologically Important γ-Lactams

✍ Scribed by Adnrew F. Parsons

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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✍ A. D'ANNIBALE; A. PESCE; S. RESTA; C. TROGOLO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Ceric Ammonium Nitrate Promoted Free Radical Cyclization Reactions Leading to β-Lactams. -Treatment of enamides (I) or (V) with cerium ammonium nitrate (CAN) generates α-carbamoyl radicals which undergo 4-exo-trig cyclization followed by methanol quenching to provide the functionalized β-lactams. T