Zirconocene-catalyzed cationic Diels-Alder reactions
β Scribed by Peter Wipf; Wenjing Xu
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 624 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
A cationic palladium(ll) complex, [PdL2(RCN)2](BF4)2, has been found to catalyze the Diels-Alder reaction of a, r-unsaturated carbonyl compounds with dienes, affording the corresponding cycloadducts in good yields. Excellent enantioselectivity can be achieved in the reaction of Nacryloyloxazolidinon
The first examples of intramolecular cation radical Die&-Alder reactions have been established using trienes which cyclize to hydroindane systems. The extremely high endo stereoselectivity characteristic of the cation radical Diels-Alder reaction is effectively exploited to generate trans-hydroinda
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