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A cationic palladium(II) complex-catalyzed Diels-Alder reaction

✍ Scribed by Shuichi Oi; Kenji Kashiwagi; Yoshio Inoue

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
179 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

A cationic palladium(ll) complex, PdL2(RCN)22, has been found to catalyze the Diels-Alder reaction of a, r-unsaturated carbonyl compounds with dienes, affording the corresponding cycloadducts in good yields. Excellent enantioselectivity can be achieved in the reaction of Nacryloyloxazolidinone and cyclopentadiene by use of a chiral ligand, BINAP.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Hetero D
ChemInform Abstract: Asymmetric Hetero Dielsβ€”Alder Reaction Catalyzed by Chiral Cationic Palladium(II) and Platinum(II) Complexes.
✍ Shuichi Oi; Eiji Terada; Kazuei Ohuchi; Tomoko Kato; Yukari Tachibana; Yoshio In πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

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