ChemInform Abstract: Asymmetric Hetero Diels—Alder Reaction Catalyzed by Chiral Cationic Palladium(II) and Platinum(II) Complexes.
✍ Scribed by Shuichi Oi; Eiji Terada; Kazuei Ohuchi; Tomoko Kato; Yukari Tachibana; Yoshio Inoue
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Asymmetric Hetero-Diels-Alder Reactions Catalyzed by Chiral (Salen)Chromium(III) Complexes. -The title reactions between (I) and a wide range of aldehydes require only 2 mol% of the catalyst and afford the pyranone derivatives (III) with good enantioselectivity. Among different derivatives of the c