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The intramolecular cation radical diels-alder reaction

✍ Scribed by Bijan Harirchian; Nathan L Bauld

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
181 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

The first examples of intramolecular cation radical Die&-Alder reactions have been established using trienes which cyclize to hydroindane systems.

The extremely high endo stereoselectivity characteristic of the cation radical Diels-Alder reaction is effectively exploited to generate trans-hydroindanes with high selectivity.

πŸ“œ SIMILAR VOLUMES

Cation radical cycloaddition polymerizat
Cation radical cycloaddition polymerization: Diels–Alder copolymerization
✍ Nathan L. Bauld; J. Todd Aplin; Wang Yueh; Stephanie Endo πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 75 KB πŸ‘ 2 views

The Diels-Alder cycloaddition copolymerization of a bis(diene) with ionizable bis(dienophiles) via a cation radical mechanism has been accomplished using tris(4-bromophenyl)aminium hexachloroantimonate as a catalyst in dichloromethane solvent. The reactions occur at 0Β°C and yield Diels-Alder polymer