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Cation radical cycloaddition polymerization: Diels–Alder copolymerization

✍ Scribed by Nathan L. Bauld; J. Todd Aplin; Wang Yueh; Stephanie Endo

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 75 KB
Volume: 11
Category: Article
ISSN: 0894-3230
DOI: 10.1002/(sici)1099-1395(1998110)11:11<825::aid-poc73>3.0.co;2-u

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✦ Synopsis

The Diels-Alder cycloaddition copolymerization of a bis(diene) with ionizable bis(dienophiles) via a cation radical mechanism has been accomplished using tris(4-bromophenyl)aminium hexachloroantimonate as a catalyst in dichloromethane solvent. The reactions occur at 0°C and yield Diels-Alder polymers of M W up to ca. 10,000 and a polydispersity index ca. 2.

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