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ChemInform Abstract: Radical Cation Diels—Alder Reaction Between Indoles and Exocyclic 1,3-Dienes with Incorporated Intentional Cleaving Points.

✍ Scribed by Thomas Peglow; Siegfried Blechert; Eberhard Steckhan


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


The photoinduced electron transfer catalyzed radical cation Diels-Alder reaction between exocyclic dienes containing an N-O or N-N bond as an intentional cleaving point in the ring moiety [cf. (IV) and (X)] and indoles provides a rapid access to highly functionalized tetrahydrocarbazole derivatives [cf.