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Zirconocene-catalyzed alkylation of aryl alkenes with alkyl tosylates, sulfates and bromides

โœ Scribed by Jun Terao; Tsunenori Watanabe; Koyu Saito; Nobuaki Kambe; Noboru Sonoda

Book ID
104260262
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
232 KB
Volume
39
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Styrenes were alkylated with alkyl tosylates, sulfates and bromides in the presence of a zirconocene catalyst and "BuMgC1 in THF. By the use of this reaction, primary and secondary alkyl groups can be introduced regioselectively at the benzylic carbon of styrenes to give a-substituted ethylbenzenes.

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โœ Jun Terao; Tsunenori Watanabe; Koyu Saito; Nobuaki Kambe; Noboru Sonoda ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 2 views

Zirconocene-Catalyzed Alkylation of Aryl Alkenes with Alkyl Tosylates, Sulfates, and Bromides. -Primary and secondary alkyl groups can be introduced regioselectively at the benzylic position of styrenes by alkylation in the presence of catalytic amounts of zirconocene catalysts.

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