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Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Sulfamates and Tosylates

✍ Scribed by Agrawal, Toolika; Cook, Silas P.


Book ID
120075828
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
446 KB
Volume
15
Category
Article
ISSN
1523-7060

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Silver-catalyzed cross-coupling reaction
✍ Hidenori Someya; Hideki Yorimitsu; Koichiro Oshima πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 958 KB

Treatment of secondary or tertiary alkyl bromides with alkyl Grignard reagents in the presence of catalytic amounts of silver bromide and potassium fluoride in CH 2 Cl 2 afforded the corresponding cross-coupling products in reasonable yields. Moreover, silver showed catalytic activity for the cross-