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Zinc-prolinamide complex catalyzed direct asymmetric aldol reactions in the presence of water

✍ Scribed by ZhiJin Lu; HaiBo Mei; GuangQian Zhang; JianLin Han; Yi Pan


Book ID
107349204
Publisher
SP Science China Press
Year
2010
Tongue
English
Weight
448 KB
Volume
53
Category
Article
ISSN
1674-7291

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Direct Catalytic Asymmetric Aldol Reacti
✍ Joanna Paradowska; Maciej Stodulski; Jacek Mlynarski πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Direct Catalytic Asymmetric Aldol Reacti
✍ Joanna Paradowska; Maciej Stodulski; Jacek Mlynarski πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 94 KB πŸ‘ 2 views

## Abstract A combination of zinc triflate and chiral __C~2~__‐symmetrical prolinamide ligand leads to high enantioselectivities in direct aldol reactions essentially assisted by water. The presence of 5 mol % of the catalyst affords an asymmetric intermolecular aldol reaction between unmodified ke