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Zinc, penicillamine, and prostaglandin e1

✍ Scribed by D. F. Horrobin; M. S. Manku; S. C. Cunnane; M. Karmazyn; A. I. Ally; R. O. Morgan; R. A. Karmali

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
88 KB
Volume
21
Category
Article
ISSN
0004-3591

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An asymmetric total synthesis of Prostaglandin E 1 (5) has with the Corey CBS catalyst gave the Ο‰-side chain 7 with ΟΎ96% ee. Conjugate addition using the reaction with been achieved in a two-component coupling process. The chiral hydroxycyclopentenone 6 was readily available from dilithiocyanocuprat